IPA: /ˌʌn.səkˈsɛs.fəl/
KK: /ʌnˈsʌk.sɛs.fəl/
Not achieving the desired result or goal; failing to succeed.
Despite her hard work, she was unsuccessful in getting the promotion.
Unsuccessful → It is formed from "un-" (meaning not) and "success" (from Latin "successus", meaning to come close or to achieve). The word "unsuccessful" means not achieving a desired outcome or goal.
Think of 'not' ('un-') achieving something ('success') — that's why unsuccessful means failing to achieve.