IPA: //ʌnˈskɛdʒ.uːld//
KK: /ʌnˈskɛdʒʊld/
Not planned or arranged in advance; happening without a set time.
The meeting was unscheduled, so many people were caught off guard.
Unschedule → It is formed from "un-" (meaning not) and "schedule" (from Old French *escheduel*, meaning a list or plan). The word "unscheduled" means not planned or not listed in a schedule.
Think of 'not' ('un-') having a 'plan' ('schedule') — that's why unscheduled means something that is not planned.