IPA: //ʌnˈnætʃərəl//
KK: /ʌnˈnætʃərəl/
Not natural; artificial or forced, often in a way that feels uncomfortable or wrong.
Her smile seemed unnatural, as if she was trying too hard to be happy.
Unnatural → It is formed from "un-" (meaning not) and "natural" (from Latin "naturalis", meaning of nature). The word "unnatural" means not in accordance with nature or not natural.
Think of 'not' ('un-') being added to 'natural', which helps you remember that 'unnatural' describes something that is not in harmony with nature.