IPA: /ˌʌnəˈkweɪntɪd/
KK: /ʌnəˈkwentɪd/
Not familiar with someone or something; lacking knowledge or experience about a particular person or topic.
She felt unacquainted with the local customs when she moved to the new city.
Unacquainted → It is formed from "un-" (meaning not) and "acquainted" (from Old French *acointier*, meaning to make known or to become familiar). The word "unacquainted" means not familiar or not known to someone.
Think of 'not' ('un-') being added to 'familiar' ('acquainted') — this helps you remember that unacquainted means not familiar with someone.