IPA: //ˌʌn.əˈkʌs.təmd//
KK: /ʌnəˈkʌstəmd/
Not familiar or used to something; not having experience with a particular situation or condition.
She felt unaccustomed to the fast pace of city life after moving from a small town.
Unaccustomed → It is formed from "un-" (meaning not) and "accustomed" (from Old French *acostumer*, meaning to make familiar or to habituate). The word "unaccustomed" means not familiar or not used to something.
Think of 'not' ('un-') being added to 'familiar' or 'used to' ('accustomed') — that's why unaccustomed means not used to something.