IPA: //səbˈstɪtʃənl//
KK: /sʌbstɪˈtuːʃənl/
Relating to the act of replacing one thing with another or using a substitute.
In chemistry, substitutional alloys are formed when one metal replaces another in the crystal structure.
Substitutional → It is formed from "sub-" (meaning under or in place of) and "stituere" (meaning to place or set). The word refers to something that is placed in the place of another, hence relating to substitution.
Think of something being 'placed in the place of' another — 'sub-' means under or in place of, and 'stituere' means to place.