IPA: /ɪmˈpɜːrviəs/
KK: /ɪmˈpɜrviəs/
Not able to be affected or harmed by something; not allowing anything to pass through.
The raincoat is made of a material that is impervious to water.
Impervious → It is formed from "in-" (meaning not) and "pervius" (from Latin, meaning passable or able to be passed through). The word "impervious" means not able to be passed through or not allowing passage.
Think of 'not' ('in-') allowing something to 'pass through' ('pervius') — that's why impervious means something that cannot be penetrated.