IPA: /ˌsɜːrkəmˈvæleɪʃən/
KK: /sɜrˌkʌmˈvæleɪʃən/
A defensive structure, like a wall or rampart, built around a place to protect it from attacks.
The ancient city was surrounded by a strong circumvallation to keep invaders out.
Circumvallation is formed from "circum-" (meaning around) and "vallare" (meaning to fortify or surround with a wall). The term refers to the act of surrounding a place with a defensive wall or fortification.
Think of 'around' ('circum-') and 'fortifying' ('vallare') something — that's why circumvallation means to fortify an area by surrounding it.
No commonly confused words.