IPA: /ˈɑːr.tʃɛn.ə.mi/
KK: /ˈɑrˌtʃɛnəmi/
A main or primary enemy, often someone who opposes or competes against another person.
In the story, the hero must confront his archenemy to save the world.
Archenemy is formed from "arch-" (from Greek "archi-", meaning chief or principal) and "enemy" (from Old French "enemi", meaning adversary or foe). The word describes a principal enemy or the most significant adversary one can have.
Think of 'arch-' meaning chief or principal, which helps you remember that an archenemy is your most significant enemy.